Synthesis and Characterization of Functionalized SBA-15 Mesoporous Silica by N, N´-Bis(salicylidene)ethylenediamine Schiff-Base

Document Type : Research Paper


Department of Chemistry, Iran University of Science and Technology, Narmak, Tehran, 16846-13114, Iran



In this work, BSEA-SBA-15 was prepared for the first time, which was prepared by covalently anchoring Schiff-base compound (N,N´-bis(salicylidene)ethylenediamine (BSEA) on SBA-15 by hydrothermal method. The structure and physicochemical properties were determined by elemental analysis, XRD, nitrogen adsorption–desorption, thermogravimetric analysis and FTIR spectroscopy, SEM, BET surface area and BJH pore size. The average pore diameter after the modification is 69Å. It is expected that BSEA-SBA-15 can be used as an effective adsorbent for the removal of metal ions due to having porous structure and active functional groups.


[1] S. Fiorilli, F. Tallia, L. Pontiroli, C. Vitale-Brovarone, B. Onida. Mater Lett. 108 (2013) 118-121.
[2] S.R. Yousefi, S.J. Ahmadi, F. Shemirani, M.R. Jamali, M. Salavati- Niasari, emission spectrometry, Talanta. 80-2009) 212-217.
[3] M.R. Jamali, Y. Assadi, F. Shemirani, M.R.M. Hosseini, R.R. Kozani, M. Masteri-Farahani, M. Salavati-Niasari, Anal. Chim. Acta. 579 (2006) 68-73.
[4] C. Kresge, M. Leonowicz, W. Roth, J. Vartuli, J. Beck, nature. 359 (1992) 710-712.
[5] D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Science. 279 (1998) 548-552.
[6] A.Y. Khodakov, V.L. Zholobenko, R. Bechara, D. Durand,  Microporous and Mesoporous Mater. 79 (2005) 29-39.
[7] A. Shahbazi, H. Younesi, A. Badiei, Chem. Eng. J. 168 (2011) 505-518.
[8] M.E. Mahmoud, I.M.M. Kenawy, MM.  A.H. Hafez, R.R. Lashein, Desalination  250 (2010) 62 -70.
[9] Mihaela Mureseanu, Aurora Reiss, Ioan Stefanescu, Elena David, Viorica Parvulescu, Gilbert Renard, Vasile Hulea Chemosphere 73 (2008) 1499-1504.
[10] M. Mureseanu, A. Reiss, N. Cioatera, I. Trandafir, V. Hulea, J. Hazard. Mater. 182   (2010) 197–203
[11] M.S. Morey, S. O'Brien, S. Schwarz, G.D. Stucky, HChem. Mater. 12 (2000) 898-911.
[12] D. Pérez-Quintanilla, I. del Hierro, M. Fajardo, I. Sierra, Microporous and Mesoporous Mater. 89 (2006) 58-68.
[13] A.B. da Silva, E. D’Elia, J.A. da Cunha Ponciano Gomes, Corros. Sci. 52 (2010) 788-793.
[14] D.L. Pavia, G.M. Lampman, G.S. Kriz, J.R. Vyvyan,  Introduction to Spectroscopy, 4th ed, Springer, 2009.
[15] S. Lowell, Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density, Springer, 2004.
[16] L. Hajiaghababaei, B. Ghasemi, A. Badiei, H. Goldooz, M. R. Ganjali, G. Mohammadi Ziarani, J. Environ. Sci. 24(7) (2012) 1347–1354.
[17] L. Hajiaghababaei, A. Badiei, M. R. Ganjali, S. Heydari , Y. Khaniani, G. Mohammadi Ziarani, Desalination 266 (2011) 182 –187.