Department of Chemistry, Payame Noor University, P. O. Box: 19395-3697, Tehran-Iran
10.7508/jns.2016.01.006
Abstract
Titanium dioxide (TiO2) nanoparticles, with an average size of about 45 nm, were encapsulated by polystyrene using in situ nitroxide mediated radical polymerization in the presence of 3-aminopropyl triethoxy silane (APTES) as a coupling agent and 2, 2, 6, 6-tetramethylpiperidinyl-1-oxy as a initiator. First, the initiator for NMRP was covalently bonded onto the surface of Titanium dioxide nanoparticles through our novel method. For this purpose, the surface of TiO2 nanoparticle was treated with 3-aminopropyl triethoxy silane, a silane coupling agent, and then these functionalized nanoparticles was reacted with ±-chloro phenyl acetyl chloride. The chlorine groups were converted to nitroxide mediated groups by coupling with 1-hydroxy-2, 2, 6, 6-tetramethyl piperidine. These modified TiO2 nanoparticles were then dispersed in styrene (St) monomers to carry out the in situ free radical polymerization.
Abbasian, M., & Khakpour Aali, N. (2016). Nitroxide-Mediated Radical Polymerization of Styrene Initiated from the Surface of Titanium Oxide Nanoparticles. Journal of Nanostructures, 6(1), 38-45. doi: 10.7508/jns.2016.01.006
MLA
M. Abbasian; N. Khakpour Aali. "Nitroxide-Mediated Radical Polymerization of Styrene Initiated from the Surface of Titanium Oxide Nanoparticles". Journal of Nanostructures, 6, 1, 2016, 38-45. doi: 10.7508/jns.2016.01.006
HARVARD
Abbasian, M., Khakpour Aali, N. (2016). 'Nitroxide-Mediated Radical Polymerization of Styrene Initiated from the Surface of Titanium Oxide Nanoparticles', Journal of Nanostructures, 6(1), pp. 38-45. doi: 10.7508/jns.2016.01.006
VANCOUVER
Abbasian, M., Khakpour Aali, N. Nitroxide-Mediated Radical Polymerization of Styrene Initiated from the Surface of Titanium Oxide Nanoparticles. Journal of Nanostructures, 2016; 6(1): 38-45. doi: 10.7508/jns.2016.01.006
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