Sol-Gel Synthesis, Characterization and Optical Properties of Bi 3+ - Doped CdO Sub-Micron Size Materials

Document Type : Research Paper

Authors

1 Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

2 School of Mechanical Engineerng WCU nano research center,Yeungnam University,Gyongsan 712-749 , South KOREA

3 Laboratory of Nano Photonics & Nano Crystals, School of Engineering-Emerging Technologies, University of Tabriz, Tabriz, Iran

4 Faculty of chemistry, Islamic Azad University, Ardabil Branch, Ardabil, Iran

10.7508/jns.2013.01.006

Abstract

Highly crystalline Bi3+-doped cadmium oxide (CdO) sub-micron structures were synthesized by calcination the obtained precursor from a sol-gel reaction. The reaction was carried out with cadmium nitrate (Cd(NO3)2.4H2O), bismuth nitrate (Bi(NO3)3.5H2O) and ethylene glycol (C2H6O2) reactants without any additives at 80°C for 2h. Resulting gel was calcined at 900 °C with increasing temperature rate of 15°C per minute for 12 h in a furnace. As a result of heating, the organic section of gel was removed and Bi3+-doped cadmium oxide micro structure was produced. The obtained compound from the sol-gel technique possesses a cubic crystalline structure at micro scale. Powder x-ray diffraction (PXRD) study indicated that the obtained Bi3+-doped CdO has a cubic phase. Also, SEM images showed that the resulting material is composed of particles with the average diameter of 1 µm. Also, UV–vis and FT-IR spectroscopies were employed to characterize the Bi3+-doped CdO micro structures.

Keywords

References

[1] L. Ying, w. Changzhen, J. rare earths. 26 (2008) 337-340.
[2] Zhen. Qiang, M. Girish, le. Ka, Shi. Gang, Li. Rong, He. Weiming, Liu. Jianqiang, Sol. State Ion. 176 (2005) 2727-2733.
[3] Xie. Jimin, Lu. Xiaomeng, Chen. Min, Zhao. Ganqing, Song. Yuanzhi, Lu. Shuaishuai, Dyes and Pig. 77 (2008) 43-47.
[4] Wu. Xiaohong, Qin. Wei, L. Li, Guo. Yun, Xie. Zhaoyang, Catal. Com. 10 (2009) 600-604.
[5] CH. Champness, CH. Chan, Sol. Energy Mater. Sol. Cells. 37 (1995) 72-75.
[6] X. Liu, Z. Xu, Y. Shen, Lisbon. (1997) 585-587.
[7] M. Ortega, G. Santana, A. Morales-Acevedo, Solid State Electron. 44 (2000) 1765-1769.
[8] R. Haul, D. Just, J. Appl. Phys. 33 (1962) 487-493.
[9] B.J. Zheng, J.S. Lian, L. Zhao, Q. Jiang, Optical and electrical properties of Sn-doped CdO thin films obtained by pulse laser deposition. Appl Surf Sci 85 (2011) 861-865.
[10] F. Dagdelen, Z. Serbetci, R.K. Gupta, F. Yakuphanoglu, Mater. Lett. 80 (2012) 127-130.
[11] M. Benhaliliba, C.E. Benouis, A. Tiburcio-Silver, F. Yakuphanoglu, A. Avila-Garcı´a, A. Tavira, R.R. Trujillo, Z. Mouffak, J. Lumin. 132 (2012) 2653-2656.
[12] NeseKavasoglu, A. Sertap Kavasoglu, Sener Oktik, J. Phys. Chem. Sol. 70 (2009) 521-525.
[13] A.A. Dakhel, Thin Solid Films. 518 (2010) 1712-1715.
[14] R.K. Gupta, K. Ghosh, R. Patel, P.K. Kahol, Appl. Surface Science. 255 (2008) 2414-2418.
[15] C. Ruvalcaba-Cornejo, M. Flores-Acosta, Ma. Elena Zayas, R. Lozada-Morales, J. Lumin. 128 (2008) 213-214.
[16] Varghese. Neenu, L.S. Panchakarla, M. Hanapi, A. Govindaraj, C.N.R. Rao, Mater. Research Bul. 42 (2007) 2117-2120.
[17] A.A. Dakhel, Solid State Sciences. 13 (2011) 1000-1005.
[18] A.A. Dakhel, Mater. Chem. Phys. 117 (2009) 284-287.
[19] A.A. Dakhel, Mater. Chem. Phys. 130 (2011) 398-402.
[20] Kose. Salih, Atay. Ferhunde, Bilgin. Vildan, Akyuz. Idris, Inter. J. hydrogen energy. 34 (2009) 5260-5266.
[21] A.A. Dakhel, Optical Mater. 31 (2009) 691-695.
[22] Kul. Metin, Zor. Muhsin, Aybek. Ahmet Senol, Irmak. Sinan, Evren Turan, Sol. Energy Mater. Sol. Cells. 91 (2007) 882-885.
[23] R.J. Deokate, S.V. Salunkhe, G.L. Agawane, B.S. Pawar, S.M. Pawar,  J. Alloys and Comp. 496 (2010) 357-363.
[24] R.K. Gupta, K. Ghosh, R. Patel, P.K. Kahol, J. Alloys and Comp. 509 (2011) 4146-4149.
[25] R.K. Gupta, Z. Serbetc, F. Yakuphanoglu, J. Alloys and Comp. 515 (2012) 96-99.
[26]N. Ozdemir, M. Cavas, Ahmed A. Al-Ghamdi, Zarah H.Gafer, F. El-Tantawy and F. Yakuphanoglu. Proceedings of Global Engineering, Science and Technology Conference. 1 - 2 April, Dubai, UAE, ISBN: 978-1-922069-21-4 (2013).
[27] R. Maity, K.K. Chattopadhyay, Sol. Energy Mater. Sol. Cells. 90 (2006) 597-606.
 [28]Z.A. Alahmed, Z. Serbetçi and F. Yakuphanoglu. Acta physica polonica A. 124 (2013).
[29]A. A. Dakhel. Eur. Phys. J. Appl. Phys. 45, (2009) 20303.
[30]Quan Gu, Huaqiang Zhuang, Jinlin Long, Xiaohan An, Huan Lin, Huaxiang Lin, and Xuxu Wang. International Journal of Photoenergy. 2012 (2012), Article ID 857345, 7 pages.
[31]S. Amutha, R. Chandiramouli and B.G. Jeyaprakash. Journal of Applied Sciences, 12, (2013) 1641-1645.
[32]F. Yakuphanoglu. Solar Energy - solar energ. 85, (2011) 2704-2709.
[33] A.A. Dakhel, J. Alloys and Comp. 475 (2009) 51-54.
[34] Zhang. Lisha, Wang. Wenzhong, Yang. Jiong, Chen. Zhigang, Applied Catalysis A: General. 308 (2006) 105-110.
[35] Prasad Manjusri. Sirimanne, Takahashi. Kazunori, Sonoyama. Noriyuki, Sakata. Tadayoshi, Sol. Energy Mater. Sol. Cells. 73 (2002) 175-187.
[36] Wang. Changhua, Shao. Changlu, Wang. Lianjia, Zhang. Lina, Li. Xinghua, Liu. Yichun, J. Colloid and Interface Science. 333 (2009) 242-248.
[37] D. Ling. Christopher, J. Solid State Chem. 177 (2004) 1838-1846.
[38] Woo. Kim. Hyoun, Thin Solid Films. 516 (2008) 3665-3668.
[39] H.B. Lu, L. Liao, H. Li, Y. Tian, D.F. Wang, J.C. Li, Q. Fu, B.P. Zhu, Y. Wu, Mater. Lett. 62 (2008) 3928-3930.
[40] Aksoy. Seval, Caglar. Yasemin, Ilican. Saliha, Caglar. Mujdat, Inter. J. hydrogen energy. 34 (2009) 5191-5195.
[41] O. Vigil, F. Cruz, A. Morales-Acevedo, G. Contreras-Puente, L. Vaillant, G. antana, Chem. and Phys. 68 (2001) 249-252.
[42] A.A. Dakhel, Thin Solid Films. 517 (2008) 886-890.
[43] R.R. Salunkhe, V.R. Shinde, C.D. Lokhande, Sensors and Actuators: B. 133 (2008) 296-301.
[44] Fahrettin. Yakuphanoglu, Mujdat. Caglar, Yasemin. Caglar, Saliha. Ilican,  J. Alloys and Comp. 506 (2010) 188-193.
[45] A. Alemi, S. W. Joo, S. Khademinia, M. Dolatyari, A.Bakhtiari, h.moradi. submitted manuscript. International nano letters. (2013).
[46] T.P. Gujar, V.R. Shinde, Kim. Woo.Young. Jung, C.D. Kwang. Deog, Oh. Shim. Joo, Lokhande, Applied Surface Science. 254 (2008) 3813-3818.
[47] S. Ashoka., P. Chithaiah., G.T. Chandrappa, Mater. Letters. 64 (2010) 173-176.
[48] M. Ristic, S. Popovic, S. Music, Mater. Letters. 58 (2004) 2494-2499.
[49] A. Tadjarodi, M. Imani, Mater. Letters. 65 (2011) 1025-1027.

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