Nano-TiCl4.SiO2: A Versatile and Efficient Catalyst for Synthesis of 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes

Document Type : Research Paper

Authors

1 Department of Chemistry, College of Science, Yazd University, Yazd, PO Box 89195-741, I. R. Iran.

2 Deprtment of Organic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, I. R. Iran.

10.7508/jns.2013.04.011

Abstract

Nano-silica supported titanium tetrachloride (TiCl4.SiO2) was prepared and used as an acid catalyst for the 14-aryl or alkyl-14H-dibenzo[a,,j]xanthenesreaction under solvent-free conditions. Compared to the classical 14-aryl or alkyl-14H-dibenzo[a,j]xanthenesreaction conditions, this method consistently has the advantage of excellent yields, mild reaction conditions, ease of workup, survival of different functional groups and short reaction times.

Keywords

References

[1] D.P. Sheng, I.O.Kady, Appl. Catal. A. 365 (2009) 149-152.
[2] J.L. Souza, F. Fabri, R. Buffon, R. Schuchardet, Appl. Catal. A. Gen. 323 (2007) 223-234.
[3] R.W.Lambert, J.A. Martin, J.H. Merrett, K.E.B. Parkes, G.J. Thomas, PCT Int. Appl. WO 9706178, 1997; Chem. Abstr., 126 (1997) 212377y.
[4] T. Hideo, Chem. Abstr.95 (1981) 80922b.
[5] J.P. Poupelin, G. Saint-Ruf, O. Foussard-Blanpin, G. Narcisse, G. Uchida-Ernouf, R. Lacroix, Eur. J. Med. Chem. 13 (1978) 67-71.
[6] R.M. Ion, Prog. Catal. 2 (1997) 55-76.
[7] G. Saint-Ruf, A. De, H.T. Hieu, Bull. Chim. Ther. 7 (1972) 83-86.
[8] S.M. Menchen, S.C. Benson, J.Y.L. Lam, W. Zhen, D. Sun, B.B. Rosenblum, S.H. Khan, M. Taing, Chem. Abstr. 139 (2003) 54287f.
[9] C.G. Knight, T. Stephens, Biochem. J.258 (1989) 683-687.
[10] O. Sirkeeioglu, N. Talinli, A. Akar, J. Chem. Res. (1995) 502-506.
[11] D. Quintas, A.Garcia, D. Dominguez, Tetrahedron Lett. 44 (2003) 9291-9294.
[12] D.W. Knight, P.B. Little, Synlett.(1998) 1141-1143.
[13] A. Jha, J. Beal, Tetrahedron Lett. 45 (2004) 8999-9001.
[14] A. Bekaert, J. Andrieux, M. Plat, Tetrahedron Lett. 33 (1992)\ 2805-2806.
[15] J.A. Van Allan, D.D. Giannini, T.H. Whitesides, J. Org. Chem. 47 (1982) 820-823.
[16] M. Seyyedhamzeh, P. Mirzaei, A. Bazgir, Dyes Pigments. 76 (2008) 836-839.
[17] H.R. Shaterian, M. Ghashang, A. Hassankhani, Dyes Pigments.76 (2008) 564-568.
[18] G. ImaniShakibaei, P. Mirzaei, A. Bazgir, Appl. Catal. A: Gen. 325 (2007) 188-192.
[19] M.A. Pasha, V.P. Jayashankara, Bioorg. Med. Chem. Lett. 17 (2007) 621-623.
[20] M.A. Bigdeli, M.M. Heravi, G.H. Mahdavinia, J. Mol. Catal. A: Chem. 275 (2007) 25-29.
[21] M.M. Amini, M. Seyyedhamzeh, A. Bazgir, Appl. Catal. A: Gen. 323 (2007) 242-245.
[22] M.A. Bigdeli, M.M. Heravi, G. HosseinMahdavinia, Catal. Commun. 8 (2007) 1595-1598.
[23] W. Su, D. Yang, C. Jin, B. Zhang, Tetrahedron Lett. 49 (2008) 3391-3394.
[24] A. Khojastehnezhad, A.G. Davoodnia, M. Bakavoli, N. Tavakoli-Hoseini, M. Zeinali-Dastmalbaf, Chinese. J. Chem. 29 (2011) 297-302.
[25] B.F. Mirjalili, A. Bamoniri, L. Zamani, ScientiaIranica. doi:10.1016/j.scient.2011.12.013
[26] B.F. Mirjalili, A. Bamoniri, L. Zamani, Lett. Org. Chem. 9 (2012) 338-243.
[27] B.F. Mirjalili, A. Bamoniri, A. Akbari,Tetrahedron Lett.49 (2008) 6454-6456.
[28] B. Sadeghi, B.F. Mirjalili, M.M. Hashememi, Tetrahedron Lett. 49 (2008) 3391-3394.
Journal of Nanostructures
Volume 3, Issue 4 - Serial Number 4
December 2013
Pages 461-466

Files

Share

How to cite

Statistics