Preparation and Application of MnO2 Nanoparticles/Zeolite AgY Composite Catalyst by Confined Space Synthesis (CSS) Method for the Desulfurization and Elimination of SP and OPP

Sadeghi, M.; Hosseini, M. H.

doi:10.7508/jns.2012.04.006

Preparation and Application of MnO2 Nanoparticles/Zeolite AgY Composite Catalyst by Confined Space Synthesis (CSS) Method for the Desulfurization and Elimination of SP and OPP

Document Type : Research Paper

Authors

M. Sadeghi ¹

M. H. Hosseini ²

¹ Department of Chemistry, Faculty of Sciences, Imam Hossein University, Tehran, Iran

² Department of Chemistry, Faculty of Sciences, Imam Hossein University, Tehran, Iran b Nano Center Research, Imam Hossein University, Tehran, Iran

10.7508/jns.2012.04.006

Abstract

In this work, zeolite NaY was prepared by hydrothermal method. Then, silver ions were replaced in the zeolite NaY with silver nitrate (AgNO3) solution via using ion exchange (IE) method. The Manganese dioxide (MnO2) nanoparticles (9.3 and 15.8 wt %) for guest were deposited in the zeolite AgY(host) structure with Mn(NO3)2 aqueous and KMnO4 solutions by confined space synthesis (CSS) method. Synthesized samples were studied and characterized via XRD, SEM/EDAX, FTIR, AAS and N2-BET techniques. The desulfurization and elimination reaction of 2- chloroethyl phenyl sulfide (2-CEPS) and DEPPT (O, S-diethyl phenyl phosphonothioate) have been investigated by 15.8 wt% Nano MnO2/Zeolite AgY composite and MnO2 nanoparticles catalysts and via GC, GC-MS and 31 PNMR.

Keywords

Y-Zeolite

Composite

2-Chloroethyl phenyl sulfide O

S-diethyl phenyl

Phosphonothioate