Li + Modified Nanoporous Na+ -Montmorillonite an Efficient Novel Catalytic System for Synthesis of Quinolines

Document Type: Research Paper

Authors

1 Young Researchers and Elites Club, Rasht Branch, Islamic Azad University, Rasht, Iran,

2 Young Researchers and Elites Club, Ardabil Branch, Islamic Azad University, Ardabil, Iran

10.7508/jns.2014.03.011

Abstract

A simple and efficient method for the synthesis of quinolines and polycyclic quinolines using Li+ modified nanoporous Na+-montmorillonite is described. This new nanocatalyst proceeds via Friedlander annulation under solvent-free conditions. It describes our observations about a trend of catalytic activity of Lithium cation in nanoporous Na+-montmorillonite. In this study, several types of 1,3-diketones such as 1,3-cyclohexanedione, 1,3-cyclopentandione, 5,5-dimethylcyclohexandione (dimedone), acetylacetone and ethyl or methyl acetoacetate and 2-aminoarylketones were rapidly converted to the corresponding substitutedquinoline derivatives in good to excellent yields. The simple experimental procedure, solvent-free reaction conditions, good yields, and utilization of an inexpensive and reusable catalyst are the advantages of the proposed method. To the best of our knowledge, this is the first report on the synthesis of quinoline derivatives using Li+ modified in nanoporous Na+-MMT as a novel nanocatalyst under solvent-free conditions.The catalysts can be recovered for the subsequent reactions and reused without any loss of efficiency.

Keywords


[1] (a) G. Roma, M. D. Braccio, G. Grossi, F. Mattioli, M . Ghia, J. Med. Chem. 35 (2000) 1021-1035; (b) R. D. Larsen, E. G. Corley, A. O. King, J. D. Carrol, P. Davis, T. R. Verhoeven, P. J. Reider, M. Labelle, J. Y. Gauthier, Y. B. Xiang, R. J. Zamboni, J. Org. Chem. 61 (1996) 3398-3405; (c) D. Doube, M. Blouin, C. Brideau, C. Chan, S. Desmarais, D. Eithier, J. P. Falgueyret, R. W. Friesen, M. Girrard, Y. Girard, J. Guay, P. Tagari, R. N. Young, Bioorg. Med. Chem. Lett. 8 (1998) 1255-1260; (d) B. Kalluraya, S. Sreenivasa, Farmaco 53 (1998) 399-404; (e) I. Bennacef, C. Perrio, M. C. Lasne, L. Barre, J. Org. Chem. 72 (2007) 2161-2165; (e) A. G. Myers, N. J. Tom, M. E. Fraley, S. B. Cohen, D. J. Madar, J. Am. Chem. Soc. 119 (1997) 6072-6094; (f) M. P. Maguire, K. R. Sheets, K. McVety, A. P. Spada, A. Zilberstein, J. Med. Chem. 37 (1994) 2129-2137.

[2] (a) A. K. Agrawal, S. A. Jenekhe, Macromolecules. 24 (1999) 6806-6808; (b) X. Zhang, A. S. Shetty, S. A. Jenekhe, Macromolecules. 33 (2000) 2064-2082.

[3] (a) I. Saito, S. Sando, K. Nakatani, Bioorg. Med. Chem. 9 (2001) 2381-2385; (b) C. He, S. J. Lippard, J. Am. Chem. Soc. 40 (2001) 1414-1420.

[4] G. Jones, In Comprehensive Heterocyclic Chemistry II; A. R. Katritzky, C. W. Rees, E. F. V. Scriven, Eds.; Pergamon: New York, 1996; Vol. 5, p 167-243.

[5] C. S. Cho, B. H. Oh, T. J. Kim, S. C. Shim, Chem. Commun. (2000) 1885-1886.

[6] B. Jiang, Y. C. Si, J. Org. Chem. 67 (2002) 9449-9451.

[7] H. Skraup, Chem. Ber. 13 (1880) 2086-2087.

[8] P. Friedlander, Chem. Ber. 15 (1882) 2572-2575.

[9] R. H. F. Mansake, M. Kulka, Org. React. 7 (1953) 59-72.

[10] R. J. Linderman, S. K. Kirollos, Tetrahedron Lett. 31 (1990) 2689-2692.

[11] M. E. Theoclitou, L. A. Robinson, Tetrahedron Lett. 43 (2002) 3907-3910.

[12] (a) S. Gladiali, G. Chelucci, M. S. Mudadu, M. A. Gastaut, R. P. Thummel, J. Org. Chem. 66 (2001) 400-405; (b) C. C. Cheng, S.J. Yan, Org. React. 28 (1982) 37-201.

[13] E. A. Fehnel, J. Heterocycl. Chem. 31 (1967) 565-570.

[14] (a) Y. Z. Hu, G, Zang, R. P. Thummel, Org. Lett. (2003) 2251-2253; (b) L. Sterkowski, A. Czamy, J. Fluorin. Chem. 104 (2000) 281-284.

[15] A. Tarlani , M. Abedini, M. Khabaz, M. MohammadpourAmini, J. Colloid Interface Sci. 292 (2005) 486-492.

[16] J. S. Yadav, P. Purushothama Rao, D. Sreenu, R. Srinivasa Rao, V. Naveen Kumar, K. Nagaiah, A. R. Prasad, Tetrahedron Lett. 46 (2005) 7249-7253.

[17] M. Dabiri, S. Bashiribod, Molecules 14 (2009) 1126-1133.

[18] M. Dabiri, M. Baghbanzadeh, M. S. Nikcheh, Monatsh. Chem .138 (2007) 1249-1252.

[19] D. S. Bose, R. K. Kumar, Tetrahedron Lett. 47 (2006) 813-816.

[20] S. K. De, R. A. Gibbs, Tetrahedron Lett. 46 (2005) 1647-1649.

[21] B. R. McNaughton, B. L. Miller, Org. Lett. 5 (2003) 4257-4259.

[22] G. Wu Wang, C. Sheng Jia, Y. Wei Dong, Tetrahedron Lett. 47 (2006) 1059-1063.

[23] M. A. Zolfigol, P. Salehi, A. Ghaderi, M. Shiri, Catal. Commun. 8 (2007) 1214-1218.

[24] B. Das, K. Damodar, N. Chowdhury, R. A. Kumar, J. Mol. Catal. A: Chem. 274 (2007) 148-152.

[25] S. Ghassamipour, A. R. Sardarian. Tetrahedron Lett. 50 (2009) 514-519.

[26] M. Narasimhulu, T. S. Reddy, K. Chinni Mahesh, P. Prabhakar, C. Bhujanga Rao, Y. Venkateswarlu, J. Mol. Catal. A: Chem. 266 (2007) 114-117.

[27] (a) M. Dabiri, S. C. Azimi, A. Bazgir, Monatsh. Chem. 138 (2007) 659-661; (b) U. V. Desai, S. D. Mitragotri, T. S. Thopate, D. M. Pore, P. P. Wadgaonkar, arkivoc (xv) (2006) 198-204.

[28] M. Abdollahi-Alibeik, M. Pouriayevali, Catal. Commun. 22 (2012) 13-18.

[29] A. Teimouri, Al. NajafiChermahini, Arabian Journal of Chemistry, In Press, Corrected Proof, Available online 2 June 2011.

[30] (a) S. S. Palimkar, S. A. Siddiqui, T. Daniel, R. J. Lahoti, K. V. Srinivasan, J. Org. Chem. 68 (2003) 9371-9378; (b) J. Akbari, A. Heydari, H. R. Kalhor, S. Azizian Kohan, J. Comb. Chem.12 (2010) 137-140.

[31] A. Corma, H. Garcia, Chem. Rev. 103 (2003) 4307-4366.

[32] (a) G. Sharma, R. Kumar, A. K. Chakraborti. J. Mol. Catal. A: Chem. 263 (2006) 143-148; (b) C. R. Reddy, B. Vijayakumar, P. Iyengar, G. Nagendrappa, B. S. JaiPrakash, J. Mol. Catal. A: Chem. 223 (2004) 117-122; (c) C. R. Reddy, P. Iyengar, G. Nagendrappa, B. S. Jai Prakash, J. Mol. Catal. A: Chem. 229 (2005) 31-37.

[33] E. P. Giannelis, R. Krishnamoorti, E. Manias, Adv. Polym. Sci. 138 (1999) 107-147.

[34] (a) H. Shi, T. Lan, T. J. Pinnavaia, Chem. Mater. 8 (1996) 1584-1587; (b) S. Yariv, H. Cross, Organo-clay complexes and interactions, 1st edn. CRC, New York, 2002.

[35] G. Berger, ChemWeekblad 38 (1941) 42-43.

[36] (a) H. Deuel, G. Huber, R. Iberg, Helv. Chim. Acta. 33 (1950) 1229-1232; (b) J. E. Gieseking, Adv. Agron. 1 (1949) 159-204.

[37] (a) M. Dabiri, S. C. Azimi, H. R. Khavasi, A. Bazgir, Tetrahedron 64 (2008) 7307-7311; (b) K. Rad-Moghadam, M. Sharifi-Kiasaraie, S. C. Azimi, Tetrahedron 68 (2012) 6472-6476; (c) K. Rad-Moghadam, S. C. Azimi, Tetrahedron 68 (2012) 9706-9712; (d) K. Rad-Moghadam, S. C. Azimi, E. Abbaspour-Gilandeh, Tetrahedron Lett. 54 (2013) 4633-4636. (g) E. Abbaspour-Gilandeh; S. C. Azimi; K. Rad-Moghadam; A. Mohammadi-Barkchai, Iran. J. Catal. 3(2) (2013) 91-97; E. Abbaspour-Gilandeh; S. C. Azimi; K. Rad-Moghadam; A. Mohammadi-Barkchai, Iran. J. Catal. 3(1) (2013) 15-20; A. Bazgir, S. C. Azimi, Iran. J. Catal. 3(1), 2013, 21-26. (h) S. C. Azimi, H. Kefayati, Iran. J. Catal. 3(2), 2013, 123-128; S. C. Azimi; Iran. J. Catal. 4(2), 2014, 113-120.