Organic-inorganic hybrid nanomaterials prepared from 4- formyl benzo-12-crown-4-ether and silica coated magnetite nanoparticles

Document Type: Research Paper

Authors

1 Faculty of Chemistry, University of Tarbiat Moallem, Tehran, Iran

2 Faculty of Chemistry, Islamic Azad University, Ardabil branch, Ardabil, Iran

3 Chemistry Department, Faculty of Sciences, Islamic Azad University, Kermanshah, Iran

10.7508/jns.2011.03.002

Abstract

Silica  coated magnetite  nanoparticles were  covalent  grafted with  3-aminopropyl trimethoxysilane  to give APTSCMNPs. Reaction of  the resulted nanomaterial with 4-formyl benzo-12-crown-4 ether afforded FB12C4/APTSMNPs  nanocomposite  material  in  which  the  crown ether  moiety  was  attached  through  propyl  chain  spacer. Characterization of  the prepared nanocomposite was performed with different  physicochemical  methods  such  as  FT-IR  spectroscopy, thermogravimetric  analysis  (TGA-DTA),  X-ray  diffraction  (XRD), scanning  electron  microscopy  (SEM),  transmission  electron microscopy (TEM) and vibrating sample magnetometry (VSM).

Keywords


[1]   P. Mc Morn, G.J. Hutchings, Chem. Soc. Rev. 33 (2004) 108.

[2] A. Corma, H. Garcia, Adv. Synth. Catal. 348 (2006)1391.

[3] N.E. Lead beater, M. Marco, Chem. Rev. 102 (2002) 3217.

[4] P.M. Price, J.H. Clark, D.J. Macquarrie,  J. Chem. Soc. Dalton Trans. (2000)  101–110.

[5] A.P. Wight, M.E. Davis,  Chem.  Rev. 102 (2002) 3589-3614.

[6] J.E.G. Mdoe, D.J. Macquarrie, J.H. Clark, J. Mol. Catal. A: 198 (2003)  241–247.

[7]    A. Corma, Chem. Rev. 95 (1995) 559.

[8] E.F. Vansant, P. Van Der Voort and K.C. Vranken, Characterisation and Chemical Modification of the Silica Surface, Elsevier, Amsterdam, (1995).

[9] R.D. Badley, W.D. Ford, F.J. McEnroe, R.A. Assink, Langmuire, 6 (1990) 792.

[10] A.S.   Piers,   C.H.   Rochester,   J.   Chem. Soc.Faraday Trans. 91 (1995) 359.

[11] S. Kondo, T. Ishikawa, N. Yamagami, K. Yoshioka, Y. Nakahara, Bull. Chem. Soc. Jpn. 60 (1987) 95.

[12] K.C. Vrancken, P. Van Der Voort, I. Gillis- D'Hamers, E.F. Vansant, P. Grobet, J. Chem. Soc. Faraday Trans. 88 (1992)  3197.

[13] K.C. Vrancken, L. De Coster, P. Van  Der Voort, E.F. Vansant, P. Grobet, J. Colloid Interface Sci. 170 (1995) 71.

[14] B. V. Zhmd, J. Sonnefeld, J. Non-Crys. Solids, 195 (1996) 16.

[15] A.  Walkarius,  Electroanal.  10   (1998)   1217-1235.

[16] J. J.E. Moreau, M.W. Chi Man, Coord.   Chem.Rev. 178-180 (1998) 1073-1084.

[17] P.M. Price, J.H. Clark, D.J. Macquarrie, J. Chem. Soc. Dalton Trans. (2000)  101-110.

[18] J.H. Clark, D.J. Macquarrie, Chem. Commun. (1998) 853.

[19] K.  Moller,  T.  Bein,  Chem.  Mater.  10 (1998) 2950.

[20] K.S. Rao, T. Khalil El-Hami, K. Kodaki, K. Matsushige, J. Colloid Interface Sci.  289 (2005) 125.

[21] A.S. Ethiraj, N. Hebalkar, S.K. Kulkarni, R. Pasricha, J. Urban, M. Schmitt, R. Fink, J. Chem. Phys. 118 (2003) 8945.

[22] B. Sreedhar, P. Radhika, B. Neelima, N. Hebalkar,  J.  Mol.  Catal.  A:  272  (2007) 159-163.

[23] X. Liu, Z. Ma, J. Xing, H. Liu, J. Magn.  Magn. Mater. 270 (2004) 1–6.

[24] J.S. Suleiman, B. Hu, H. Peng, C. Huang, Talanta 77 (2009) 1579–1583.

[25] X. Liu, J. Xing, Y. Guan, G. Shan, H. Liu, Colloids and Surfaces A: Physicochem. Eng. Aspects 238 (2004) 127–131.

[26] D. Yang, J. Hu, S. Fu, J. Phys. Chem. C 2009, 113, 7646–7651.

[27] M. Lou, D. Wang, W. Huang , D. Chen ,  B. iu, J. Magn. Magn. Mater. 305 (2006)  83–90.

[28] J. Dong, Z. Xu, F. Wang, Appl. Surf. Sci. 254 (2008) 3522–3530.

[29] Y.H.  Deng, C.C. Wang, J.H.  Hu, W.L.   Yang, S.  K. Fu, Colloids and Surfaces A: Physicochem. Eng. Aspects 262 (2005)  87–93.

[30] R. Shi,  Y. Wang, Y.  Hu,  L. Chen, Q.H.  Wan,J. Chromatography A, 1216 (2009)  6382– 6386.

[31] F. Wada, H. Hirayama, H. Namiki, K. Kikukawa, T. Matsuda, Bull. Chem. Soc. Jpn. 53(1980)1473.